Skip Navigation

Special Report on Mineral Waters (1902)

Prev Page--Waters of Kansas--Sulfid || Next Page--Waters of Kansas--Special


Part II--The Mineral Waters of Kansas, Arranged and Classified, with Analyses, continued

Chapter XVI--Chalybeate (Iron) Group

The iron waters are usually carbonates, though the iron in some cases is regarded as a sulfate. Many of the waters here mentioned might very properly go in group IV as carbonates.

Where there is only a small quantity of sulfate in the water it is evident that the iron has come from sandstones or similar rocks, and has been reduced by the organic matter which accompanies the water in its course through the underground strata. Much of the soil contains an abundance of iron, and the waters, already charged with carbonic-acid gas holding calcium and magnesium salts in solution as bicarbonates, have only to come in contact with this iron and the rich vegetable mold to become in turn chalybeate waters.

Many shales are filled with crystals of iron pyrites, and these, under the influence of air and moisture, especially in contact with organic matter, will oxidize, forming iron sulfate. Coal itself, or partially formed coal, as peat, is readily disintegrated by the action of the decomposing sulfids. Ordinary soft coal has but to be exposed to "weathering" to fall to pieces from this same cause. This gives us "mine water," or, if shale which contains alumina has also been in contact with the decomposing material, an "alum water" is the result. It is evident that the action of an iron-sulfate water, or an iron-chlorid water--both strong astringents--would be quite different from that of an iron-carbonate water. (See p. 55 for therapeutic action.)

This group is represented by the following waters:

Arrington Springs

In the extreme southwestern part of Atchison county, in the valley of the Delaware river and quite near this stream, are situated the Arrington springs. The village is on the Leavenworth, Kansas & Western railroad, midway between Holton and Valley Falls. The springs were among the earliest developed in Kansas, for as early as 1881 improvements were made here. There are numerous springs on both sides of the Delaware river, but those that have the most abundant flow are below the bridge that spans the river, and in the vicinity of the mill. The water from one of these springs (that one nearest the bridge) was formerly piped to a bath-house situated on the north side of the bridge.

Improvements

The entire property consists of forty acres, but, on account of litigation, no improvements of any importance have been made since the earlier developments. The controlling interest in the springs was about three years ago purchased by D. S. Hencks. On the left bank of the river is a very pretty grove, in which the springs are situated. On the east side of this grove are twelve cottages. A bath-house and engine-house with steam-pump were formerly operated in connection with the springs, but since the burning of the hotel their use has been abandoned. In 1902 a new hotel was built in the village, and the intention is to again develop the springs and make the place a popular resort.

Arrington No. 1
Ions Grams
per liter
Sodium (Na) .1183
Potassium (K) .0144
Lithium (Li) .0015
Calcium (Ca) .1165
Magnesium (Mg) .0374
Iron (Fe) .0295
Chlorin (Cl) .0377
Sulfuric acid ion (SO4) .0731
Silicic acid ion (SiO3) .0210

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0622 3.633
Sodium sulfate (Na2SO4) .0351 2.056
Sodium bicarbonate (NaHCO3) .3107 18.148
Potassium bicarbonate (KHCO3) .0355 2.091
Lithium bicarbonate (LiHCO3) .0148 .864
Calcium sulfate (CaSO4) .0221 1.291
Calcium bicarbonate (CaH2(CO3)2) .2810 16.413
Magnesium sulfate (MgSO4) .0321 1.874
Magnesium bicarbonate (MgH2(CO3)2) .1766 10.315
Iron bicarbonate (FeH2(CO3)2) .0939 5.484
Silica (SiO2) .0169 .987
Ammonium crenate .0152 .887
Organic matter .0046 .268
Totals 1.1007 64.311
Temperature, 13.3° C. (56° F.)
Analysis by Juan H. Wright, M. D.

Plate 30--Cottages, Arrington Springs.

Black and white photo of Cottages, Arrington Springs.

Plate 30--Bath-house and Pavilion, Arrington Springs.

Black and white photo of Bath-house and Pavilion, Arrington Springs.

Arrington No. 2
Ions Grams
per liter
Sodium (Na) .0479
Ammonia (NH.) trace
Calcium (Ca) .0454
Magnesium (Mg) .0156
Iron (Fe) .0161
Chlorin (Cl) .0224
Silicic acid ion (SiO3) .0204

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0370 2.164
Sodium bicarbonate (NaHCO3) .0965 5.637
Calcium bicarbonate (CaH2(CO3)2) .1834 10.728
Magnesium bicarbonate (MgH2(CO3)2) .0953 5.569
Iron bicarbonate (FeH2(CO3)2) .0528 .3.084
Silica (SiO2) .0095 .555
Organic matter .0161 .911
Ammonia trace trace
Totals .4906 28.648
Analysis by Juan H. Wright, M. D.

Arrington No. 3
Ions Grams
per liter
Sodium (Na) .0136
Potassium (K) trace
Lithium (Li) trace
Calcium (Ca) .0240
Magnesium (Mg) .0622
Iron (Fe) .0399
Chlorin (Cl) .0350
Iodin (I) trace
Sulfuric acid ion (SO4) .1802
Silicic acid ion (SiO3) .0116

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0344 2.003
Potassium iodid (KI) trace trace
Lithium (Li) trace trace
Calcium sulfate (CaSO4) .0052 .308
Calcium bicarbonate (CaH2(CO3)2) .0914 5.334
Magnesium chlorid (MgCl2) .0190 1.112
Magnesium sulfate (MgSO4) .2205 12.882
Magnesium bicarbonate (MgH2(CO3)2) .0611 3.571
Iron bicarbonate (FeH2(CO3)2) .1206 7.044
Silica (SiO2) .0092 .541
Totals .5614 32.795
Analysis by Juan H. Wright, M. D.

Atchison Electric-light Well

This well is seventy-five feet deep. Iron deposits readily from this water, staining the drinking vessels.

Well of the Atchison Electric-Light and Power Plant
Grams per liter
Ions   Radicals
Sodium (Na) .0414   Sodium oxid (Na2O) .0558
Potassium (K) .0114   Potassium oxid (K2O) .0137
Calcium (Ca) .1141   Calcium oxid (CaO) .1596
Magnesium (Mg) .0254   Magnesium oxid (MgO) .0423
Iron (Fe) .0675   Iron oxid (FeO) .0867
Aluminum (Al) .0300   Aluminum oxid (Al2O3) .0567
Chlorin (Cl) .0560   Chlorin (Cl) .0560
Sulfuric acid ion (SO4) .0881   Sulfuric anhydrid (SO3) .0734
Silicic acid ion (SiO3) .0752   Silica (SiO2) .0594
    Water (H2O) .1098
    Carbonic anhydrid (CO2) .5384
    Oxygen equivalent .0126
  Total 1.2392

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0046 .2687
Sodium bicarbonate (NaHCO3) .1445 8.4402
Potassium bicarbonate (KCO3) .0292 1.7056
Calcium bicarbonate (CaH2(CO3)2) .4617 26.9679
Magnesium bicarbonate (MgH2(CO3)2) .1544 9.0185
Iron bicarbonate (FeH2(CO3)2) .2142 12.5114
Aluminum chlorid (AlCl3) .0666 3.8901
Aluminum sulfate (Al2(SO4)3) .1046 6.1097
Silica (SiO2) .0594 3.4695
Totals 1.2392 72.3816
Temperature 13.3° C. (56° F.)
Analysis by E. B. Knerr.

McDuff's Spring, Atchison

There is a spring on the farm of Mr. Peter McDuff, four and a half miles northwest of Atchison. It is situated on the north side of a ravine, where the general trend of the land is toward the east. The water issues with a pretty strong flow and gives a slight. deposit of iron oxid along the course of the stream. There is no odor of hydrogen sulfid , but a careful chemical test of the freshly-drawn water shows small quantities of this gas. In the vicinity are some very excellent and abundant springs of clear, cold, fresh water. The analysis is as follows:

McDuff's Spring
Grams per liter
Ions   Radicals
Sodium (Na) .0202   Sodium oxid (Na2O) .0272
Potassium (K) .0168   Potassium oxid (K2O) .0202
Calcium (Ca) .0840   Calcium oxid (CaO) .1176
Magnesium (Mg) .0131   Magnesium oxid (MgO) .0218
Iron (Fe) .0168   Iron oxid (FeO) .0216
Aluminum (Al) .0064   Aluminum oxid (Al2O3) .0120
Chlorin (Cl) .0240   Chlorin (Cl) .0240
Sulfur (S) .0109   Sulfuric anhydrid (SO3) .0151
Sulfuric acid ion (SO4) .0181   Hydrogen sulfid (H2S) .0116
Silicic acid ion (SiO3) .0442   Silica (SiO2) .0350
    Water (H2O) .0615
    Carbonic anhydrid (CO2) .3018
    Oxygen equivalent .0054
  Total .6640

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0200 1.1666
Sodium bicarbonate (NaHCO3) .0452 2.6365
Potassium bicarbonate (KCO3) .0430 2.5080
Calcium bicarbonate (CaH2(CO3)2) .3401 19.8400
Magnesium bicarbonate (MgH2(CO3)2) .0796 4.6430
Iron bicarbonate (FeH2(CO3)2) .0533 3.1090
Aluminum chlorid (AlCl3) .0148 .8633
Aluminum sulfate (Al2(SO4)3) .0214 1.2430
Silica (SiO2) .0350 2.0415
Hydrogen sulfid (H2S) .0116 .6766
Totals .6640 38.7275
Hydrogen-sulfid gas, trace
Specific gravity, 1.00085
Temperature 13.8° C. (57° F.)
Analysis by E. B. Knerr.

Forest Lake, Bonner Springs

Between Bonner Springs and Edwardsville, on the Union Pacific railway, about two miles below the former station, a small stream runs into the Kaw river from the north. Many years ago a dam was thrown across this stream, thus forming a pond about forty acres in extent, which now has the appearance of a natural lake, as the embankment is overgrown with grass and the banks are well wooded. This lake, known as "Forest Lake," is the property of J. W. McDanield, of Bonner Springs. On the west side the hill is somewhat precipitous and rocky, and from its summit there is a very extensive view to the east and southwest along the valley of the Kaw. The lake is used for harvesting ice in the winter, and, as it is well stocked with fish, it has become a favorite camping and fishing resort.

Improvements

Pavilions, a dancing platform, a commodious bath-house and landing-place have been erected in the grove on the west side of the lake. There are several wells or springs on the borders of the lake from which the water is drawn by means of ordinary suction-pumps. The water is clear when first drawn. and has a strong taste of iron, and in some cases of hydrogen sulfid. After the water has stood for a short time, like most chalybeate waters, it loses its carbon-dioxid gas and becomes turbid. These waters in this respect do not differ from other iron springs of the Kansas river valley.

Forest Lake Well
Grams per liter
Ions   Radicals
Sodium (Na) .0103   Sodium oxid (Na2O) .0139
Calcium (Ca) .2736   Calcium oxid (CaO) .3836
Magnesium (Mg) .0740   Magnesium oxid (MgO) .1232
Iron (Fe) .0187   Iron oxid (FeO) .0241
Chlorin (Cl) .0159   Chlorin (Cl) .0159
Sulfuric acid ion (SO4) .0600   Sulfuric anhydrid (SO3) .0500
Silicic acid ion (SiO3) .2095   Silica (SiO2) .1656
    Carbonic anhydrid (CO2) .7761
    Water (H2O) .1703
    Oxygen equivalent .0043
    Organic matter trace
  Total 1.7684

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0262 1.528
Calcium sulfate (CaSO4) .0585 3.411
Calcium bicarbonate (CaH2(CO3)2) 1.0084 58.808
Magnesium bicarbonate (MgH2(CO3)2) .4496 26.220
Iron bicarbonate (FeH2(CO3)2) .0601 3.505
Silica (SiO2) .1656 9.657
Organic matter trace trace
Totals 1.7684 103.129
Free carbon, dioxid trace
Free hydrogen sulfid, trace
Analysis by E. H. S. Bailey and D. F. McFarland

Plate 31--View on Forest Lake, Bonner Springs.

Black and white photo of View on Forest Lake, Bonner Springs.

Plate 31--Parkhurst's Iron Spring, Independence.

Black and white photo of Parkhurst's Iron Spring, Independence.

Forest Lake Iron Spring, Bonner Springs

A short distance west of the lake, just below the drive which runs to the lake, and near the dwelling occupied by the keeper, is another of the numerous iron springs of this vicinity. It is walled up and enclosed, and the water that escapes below is of the peculiar reddish color so commonly observed where iron and certain alges abound in the waters. The taste of the water is agreeable, with perhaps less iron and sulfur than that of the well previously noticed.

Forest Lake Iron Spring
Grams per liter
Ions   Radicals
Sodium (Na) .0010   Sodium oxid (Na2O) .0014
Calcium (Ca) .1804   Calcium oxid (CaO) .2526
Magnesium (Mg) .0241   Magnesium oxid (MgO) .0404
Iron (Fe) .0283   Iron oxid (FeO) .0364
Chlorin (Cl) .0016   Chlorin (Cl) .0016
Sulfuric acid ion (SO4) .0252   Sulfuric anhydrid (SO3) .0212
Silicic acid ion (SiO3) .0729   Silica (SiO2) .0575
    Carbonic anhydrid (CO2) .5073
    Water (H2O) .1031
    Oxygen equivalent .0003
  Total 1.0212

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0026 .152
Calcium sulfate (CaSO4) .0360 2.104
Calcium bicarbonate (CaH2(CO3)2) .6878 40.181
Magnesium bicarbonate (MgH2(CO3)2) .1473 8.501
Iron bicarbonate (FeH2(CO3)2) .0900 5.263
Silica (SiO2) .0575 3.369
Totals 1.0212 59.570
Temperature, 13.8° C. (57° F.)
Analysis by E. H. S. Bailey and D. F. McFarland.

Bonner Springs

Some of the springs in the park, referred to in chapter XIII, are chalybeate in character, as the following analyses show (Bull. U. S. Geol. Surv. No. 32): 77

Bonner Spring No. 4
Ions Grams
per liter
Calcium (Ca) .0802
Magnesium (Mg) .0096
Iron (Fe) .0546
Chlorid (Cl) trace
Phosphoric acid ion (PO4) trace

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Calcium chlorid (CaCl2) trace trace
Calcium bicarbonate (CaH2(CO3)2) .3243 18.942
Magnesium bicarbonate (MgH2(CO3)2) .0584 3.414
Iron bicarbonate (FeH2(CO3)2) .1735 10.135
Phosphoric acid trace trace
Organic matter trace trace
Totals .5562 32.491
Analysis by Wm. Jones, M. D.

Bonner Spring No. 5
Ions Grams
per liter
Calcium (Ca) .0936
Magnesium (Mg) .0114
Iron (Fe) .0410
Chlorin (Cl) trace
Sulfuric acid ion (SO4) .0042
Phosphoric acid ion (PO4) trace

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Calcium chlorid (CaCl2) trace trace
Calcium sulfate (CaSO4) .0059 .344
Calcium bicarbonate (CaH2(CO3)2) .3720 21.730
Magnesium bicarbonate (MgH2(CO3)2) .0696 4.065
Iron bicarbonate (FeH2(CO3)2) .1302 7.603
Phosphoric acid ion (PO4) trace trace
Organic matter trace trace
Totals .5777 33.742
Analysis by Wm. Jones, M. D.

Bonner Spring No. 6
Ions Grams
per liter
Calcium (Ca) .0578
Magnesium (Mg) .0254
Iron (Fe) .0478
Chlorin (Cl) trace
Sulfuric acid ion (SO4) .0073
Phosphoric acid ion (PO4) trace

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Calcium chlorid (CaCl2) trace trace
Calcium sulfate (CaSO4) .0103 .605
Calcium bicarbonate (CaH2(CO3)2) .2214 12.929
Magnesium bicarbonate (MgH2(CO3)2) .1570 9.172
Iron bicarbonate (FeH2(CO3)2) .1519 8.870
Phosphoric acid trace trace
Organic matter small amt. small amt.
Totals .5406 31.576
Analysis by Wm. Jones, M. D.

Coyville Ferro-manganese Well

About five miles southwest of Coyville, Wilson county, on the farm of Jacob Killion, is a bored well. The attention of the owner was attracted to the character of the water because an "oil" rose on the top after it had stood for a short time. Upon examination in the laboratory, this phenomenon was found to be due to the presence in the water of 'iron, and also a larger quantity of manganese than is usually found in natural waters. Coyville is on a branch of the Atchison, Topeka & Santa Fe railroad.

Coyville Ferro-Manganese Water, Wilson County
Grams per liter
Ions   Radicals
Sodium (Na) .0260   Sodium oxid (Na2O) .0342
Calcium (Ca) .0168   Calcium oxid (CaO) .0235
Magnesium (Mg) .0077   Magnesium oxid (MgO) .0128
Iron (Fe) .0117   Iron oxid (FeO) .0151
Manganese (Mn) .0198   Manganese oxid (MnO) .0254
Chlorin (Cl) .0390   Chlorin (Cl) .0390
Silicic acid ion (SiO3) .0304   Silicic anhydrid (SiO2) .0240
    Carbonic anhydrid (CO2) .1151
    Water (H2O) .0235
    Oxygen equivalent .0088
  Total .3038

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0643 3.756
Calcium bicarbonate (CaH2(CO3)2) .0680 3.972
Manganese bicarbonate (MgH2(CO3)2) .0468 2.734
Iron bicarbonate (FeH2(CO3)2) .0374 2.184
Magnesium bicarbonate (MgH2(CO3)2) .0633 3.697
Silica (SiO2) .0240 1.401
Totals .3038 17.744
Partial analysis by E. H. S. Bailey and F. B. Porter.

Parkhurst Spring, Independence

This spring is situated on the right bank of the Verdigris river, about a mile and a half northeast of the city of Independence. The river is beautifully shaded at this point, and a footpath leads from the spring to the bank of the river, perhaps fifty feet below. In this vicinity the Verdigris flows over rocks and shallows, and below the city (see cut) its course is turned due east by high, rocky banks. Just east of Independence the water is so deep that it furnishes ample water for a small steamboat and other light craft.

Improvements

In 1897 a road was constructed from the highway near the residence of Mr. Parkhurst, the owner of this spring, and a small pavilion was erected for the benefit of picnic parties. Beyond this no improvements have been made in the property.

Plate 32--Looking up the Verdigris, Independence.

Black and white photo of Looking up the Verdigris, Independence.

Plate 32--Louisville Springs.

Black and white photo of Louisville Springs.

The spring flows from beneath a sandstone rock, and the water deposits much iron after it comes in contact with the air. The flow of the spring in the dryest weather is about sixty gallons per hour.

Parkhurst Spring
Grams per liter
Ions   Radicals
Sodium (Na) .0725   Sodium oxid (Na2O) .0955
Calcium (Ca) .3735   Calcium oxid (CaO) .5231
Magnesium (Mg) .1668   Magnesium oxid (MgO) .2784
Manganese (Mn) .0018   Manganese oxid (MnO) .0021
Iron (Fe) .0101   Iron oxid (FeO) .1325
Sulfuric acid ion (SO4) 19.9545   Sulfuric anhydrid (SO3) 1.6718
Silicic acid ion (SiO3) .0501   Carbonic anhydrid (CO2) .1716
    Hydrogen sulfid (H2S) .0014
    Silica (SiO2) .0393
  Total 2.9157

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium sulfate (Na2SO4) .2187 12.774
Calcium sulfate (CaSO4) 1.5148 88.479
Magnesium sulfate (MgSO4) .8352 48.784
Manganese bicarbonate (MgH2(CO3)2) .0046 .271
Iron bicarbonate (FeH2(CO3)2) .2952 17.244
Silica (SiO2) .0393 2.299
Carbonic anhydrid (CO2) .0063 .373
Hydrogen sulfid (H2S) .0014 .083
Chlorin, potassium, and lithium traces traces
Totals 2.9157 170.307
Analysis by Paul Schweitzer.

La Cygne Iron Spring

This spring is situated on the west bank of the Marais des Cygnes, near La Cygne, on the property of Mr. Cheagor. The spring is not large, although it seems to be a good chalybeate water. The total solids in the water are 31.326 grains, of which 3.5 grains are ferrous carbonate. There is also a considerable quantity of calcium carbonate and magnesium carbonate, with a small quantity of calcium sulfate, sodium chlorid, and manganese carbonate.

Clarus Spring, Batesville, Woodson County

This spring is situated on the Fort Scott & Wichita rail way, nine miles west of Yates Center. The water comes from beneath a thick limestone ledge. From the situation of the spring, it is probable that there is no opportunity for the water to become in any way contaminated by organic matter. The water, as will be seen by the analysis, belongs to that class of pure waters which are recommended by physicians on account of the fact that they contain so small a quantity of mineral salts. For some time this water was kept on tap at one of the drug-stores in Topeka.

Improvements

This spring is walled up and cemented, and a small springhouse has been built over it. The flow is about forty gallons per hour. The analysis is given in chapter XVIII.

Lawrence City Water, Douglas County

The water supplied to the city of Lawrence is practically a chalybeate water. It is obtained from a large well dug in the sand a short distance west of the river, and from points that have been driven into the soil in the vicinity. The water, after it is pumped, is aerated by flowing from the top of a pipe several feet into a reservoir, and it is then allowed to stand in settling basins for some time. This treatment, however, does not fully remove the iron, for, soon after the water is drawn from the service-pipes, it loses its carbon-dioxid gas, becomes partially oxidized, and deposits a yellowish sediment of ferric hydroxid. This water is of entirely different composition from the river water, as repeated analyses have shown. Waters of this character are common in the bottoms of the Kansas and Missouri river valleys, and also in various localities in the great Mississippi basin, as has been noticed by several chemists. The sample drawn from the service-pipes does not show the full amount of iron found in the well.

Lawrence City Water Supply
Water from tap at chemistry building December 20, 1901
Grams per liter
Ions   Radicals
Sodium (Na) .0736   Sodium oxid (Na2O) .0993
Calcium (Ca) .1256   Calcium oxid (CaO) .1759
Magnesium (Mg) .0259   Magnesium oxid (MgO) .0433
Iron (Fe) .0098   Iron oxid (FeO) .0126
Chlorin (Cl) .0920   Chlorin (Cl) .0920
Sulfuric acid ion (SO4) .1063   Sulfuric anhydrid (SO3) .0902
Silicic acid ion (SiO3) .0555   Silicic anhydrid (SiO2) .0446
    Carbonic anhydrid (CO2) .3145
    Water (H2O) .0641
    Oxygen equivalent .0207
  Totals .9158

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .1518 8.861
Sodium sulfate (Na2SO4) .0428 2.501
Calcium sulfate (CaSO4) .1123 6.551
Calcium bicarbonate (CaH2(CO3)2) .3750 21.902
Magnesium bicarbonate (MgH2(CO3)2) .1582 9.241
Iron bicarbonate (FeH2(CO3)2) .0311 *1.830
Silica (SiO2) .0446 2.605
Totals .9158 53.491
Analysis by E. Bartow and J. S. Worley.
* Analyses of water from the reservoir direct
have shown considerably over two grains.

Plate 33--Suspension Bridge, Louisville.

Black and white photo of Suspension Bridge, Louisville.

Plate 33--Bathing in Rock Creek, Louisville Springs.

Black and white photo of Bathing in Rock Creek, Louisville Springs.

Louisville Springs

In Pottawatomie county, three miles north of Wamego, are situated the Louisville mineral springs. These are not far from Rock creek, a picturesque stream whose banks are well wooded. Wamego is on the main line of the Union Pacific railroad.

Improvements

A park, which is the property of R. M. Chilcott, is connected. with the village by a suspension foot bridge over Rock creek. Just below this bridge a dam has been thrown across the stream, and the swift water below the dam, at a ford on the old Pike's Peak trail, has washed away the soil and left bare the level limestone rock over a large area. This same stratum of rock that is here exposed extends northwest under the park and springs. On account of the level, smooth bottom in the pool below the dam, this pool is a favorite bathing place, especially when the water in the stream is high. Above the dam the slack water, which extends up about five miles, affords excellent boating and fishing facilities.

By sinking over the spring a tile twenty-four inches in diameter down to bed-rock, the spring-water has been made more accessible, and can be raised to a platform above by an ordinary pump. Although the water when first drawn is perfectly clear and transparent, in a short time it becomes yellow in color and very turbid. Boiling the water also causes a heavy deposit. The taste of the water is somewhat astringent, and occasionally it has a slight odor of hydrogen sulfid when it is freshly drawn. The water when evaporated has a somewhat alkaline reaction.

The analysis shows that the water is chalybeate, and also belongs to the class known as alkaline waters. From a medicinal point of view, its most important ingredients are magnesium bicarbonate, iron bicarbonate, and sodium sulfate. This water has the advantage of containing sodium salts not mixed with a large excess of salt, as is the case with many magnesium waters. On account of the presence of iron bicarbonate in the water, it is not adapted to shipping without being first carbonated. There are other chalybeate springs in this park the waters of which have not been analyzed. A few rods below the ford, on the right bank of the stream, there is a spring of extremely pure water flowing from beneath the limestone rock. Like some other pure waters that have been found in this state, it would probably be valuable in the treatment of diseases where an abundance of soft water is required.

Louisville Spring
(Kans. Univ. Quart., vol. VI, pp. 117-119)
Grams per liter
Ions   Radicals
Potassium (K) .0043   Potassium oxid (K2O) .0052
Sodium (Na) .0597   Sodium oxid (Na2O) .0805
Calcium (Ca) .2709   Calcium oxid (CaO) .3817
Magnesium (Mg) .0558   Magnesium oxid (MgO) .0932
Iron (Fe) .0198   Iron oxid (FeO) .0255
Chlorin (Cl) .0385   Chlorin (Cl) .0385
Sulfuric acid ion (SO4) .1544   Sulfuric anhydrid (SO3) .1389
Nitric acid ion (NO3) trace   Nitric anhydrid (N2O5) trace
Silicic acid ion (SiO3) .0587   Silica (SiO2) .0464
    Water (H2O) .1558
    Carbonic anhydrid (CO2) .7632
    Oxygen equivalent .0090
  Total 1.7199

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0636 3.7148
Sodium nitrate (NaNO3) trace trace
Sodium carbonate (NaHCO3) .0193 1.1273
Sodium sulfate (Na2SO4) .0996 5.8176
Potassium sulfate (K2SO4) .0096 .5607
Calcium sulfate (CaSO4) .1324 7.7334
Calcium bicarbonate (CaH2(CO3)2) .9465 55.2855
Magnesium bicarbonate (MgH2(CO3)2) .3393 19.8185
Iron bicarbonate (FeH2(CO3)2) .0632 3.6915
Silica (SiO2) .0464 2.7102
Totals 1.7199 100.4593
Temperature, 13.3° C. (56° F.)
Analysis by E. H. S. Bailey.

Plate 34--The Ford, Louisville Springs.

Black and white photo of The Ford, Louisville Springs.

Plate 34--Topeka Mineral Wells.

Black and white photo of Topeka Mineral Wells.

Mahaska Well, Washington County

This well is on the property of J. L. Summers, on the bank of a ravine, bordering the high prairie. The well is twenty feet deep, and is dug down to the solid rock, When this rock was reached it was drilled through with a hand drill, and the well filled rapidly to the depth of twelve feet.

This is a sulfate water containing small quantities of carbonates of lime and magnesia. It is slightly astringent in taste, on account of the iron that is present. One liter, on evaporation, leaves 159.27 grains of mineral matter, so the water contains a considerable quantity of sulfates. When first drawn the water is clear, but soon becomes yellow and turbid from the precipitation of iron. On this account the use of the water for household purposes has been abandoned, although it is still used for watering stock.

Muscotah Artesian Wells, Atchison County

(Trans. Kans. Acad. Sci., vol. XVII, pp. 53, 54.

by E. B. Knerr

"Along the base of the east bluff of the Grasshopper valley, about one and a half miles south of Muscotah, on the Central Branch Missouri Pacific railroad, there is a series of interesting. low ; marshy mounds. The mounded area on the farm of Mr. H. M. Rice is about one hundred rods long by fifteen rods wide, and the mounds are from five to eight feet high. About a quarter of a mile further south, on S. H. Hubbard's farm, is another mound, about fifteen yards wide, sixty yards long, and eight or ten feet high. Two miles further south, on J ames Miller's place, there are similar mounds. A swamp is usually low ground, but here the swampy ground is the highest.

"Early in September, 1900, Mr. Rice concluded that if he were to sink a pipe near one of these mounds, he would get an artesian flow of water. He bored a test hole with a two-inch auger, and at a depth of thirty-four feet struck a flow of water so strong as to force. up pebbles the size of a hickory-nut. A two-inch pipe was forced into the hole, and the water rose to overflow this when it stood fifteen feet above ground. The flow from this two-inch pipe is fifty gallons every fifty-five seconds. The water is as clear as crystal, very palatable, and cold. The water deposits a slight iron coating over the barrel into which it flows. Calcareous deposits are also found in places about the mound, indicating mineral properties for the water.

"The formation of mounds is explained by the water pressure carrying up sand and soil and depositing it at the surface. The mounds are covered by bulrushes, cat-tails and other usual swamp growth, which holds the soil, preventing its being washed down. The water springs from over the whole surface of the mound, and runs away in small streams. Thus the peculiar circumstance arises that the swamp is high ground and the firm soil is lower."

Artesian Well, Muscotah
Grams per liter
Ions   Radicals
Sodium (Na) .0181   Sodium oxid (Na2O) .0244
Potassium (K) .0203   Potassium oxid (K2O) .0245
Calcium (Ca) .1160   Calcium oxid (CaO) .1625
Magnesium (Mg) .0214   Magnesium oxid (MgO) .0356
Iron (Fe) .0360   Iron oxid (FeO) .0454
Chlorin (Cl) .0176   Chlorin (Cl) .0176
Sulfuric acid ion (SO4) .0660   Sulfuric anhydrid (SO3) .0550
Silicic acid ion (SiO3) .0305   Silicic anhydrid (SiO2) .0280
    Carbonic anhydrid (CO2) .3644
    Water (H2O) .0746
    Oxygen equivalent .0040
  Total .8280

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0290 1.6907
Sodium sulfate (Na2SO4) .0206 1.2010
Potassium sulfate (K2SO4) .0453 2.6410
Calcium bicarbonate (CaH2(CO3)2) .4702 27.4126
Magnesium sulfate (MgSO4) .0339 1.9764
Magnesium bicarbonate (MgH2(CO3)2) .0887 5.1712
Iron bicarbonate (FeH2(CO3)2) .1123 6.5471
Silica (SiO2) .0280 1. 6324
Totals .8280 48.2724
Temperature 13.3° C. (56° F.)
Analysis by E. B. Knerr.

Topeka Mineral Well

This well, which is in the rear of 316 Harrison street, was bored through thirty feet of soil and twenty-five feet of rock. The well above the rock is three feet in diameter and the pump is cemented to the opening in the rock.

Improvements

Improvements are a commodious bath hotel with a pumping plant, tanks, arrangements for heating the water, cooling rooms, etc. Special attention has been paid to giving steam and Russian baths. The water is all used commercially.

Topeka Mineral Well
(Mineral Waters of the United States, Crook, pp. 246, 247)
Ions Grams
per liter
Sodium (Na) .2803
Ammonium .0070
Calcium (Ca) .0953
Magnesium (Mg) .100.3
Iron (Fe) .1514
Aluminum (Al) .0036
Chlorin (Cl) .3732
Sulfuric acid ion (SO4) .4385
Silicic acid ion (SiO3) .2230
Phosphoric acid ion (PO4) trace
Nitric acid ion (NO3) .0244

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium sulfate (Na2SO4) .3296 19.25
Sodium nitrate (NaNO3) .0332 1.94
Sodium bicarbonate (NaHCO3) .6109 35.68
Ammonium sulfate (NH4)2SO4) .0256 1.50
Calcium bicarbonate (CaH2(CO3)2) .3853 22.51
Magnesium chlorid (MgCl2) .2016 11.78
Magnesium sulfate (MgSO4) .2465 14.40
Iron bicarbonate (FeH2(CO3)2) .4811 28.10
Alumina (Al2O3) .0068 .40
Silica (SiO2) .1765 10.30
Organic matter .0302 1.76
Phosphoric acid ion (PO4) trace trace
Totals 2.5273 147.62
Temperature, 15° C. (59° F.)
Analysis by Barnes and Sim.

Capital Mineral Well, Topeka

This well is situated at 1018 Kansas avenue, in the thickly populated portion of the city. The well is seventy feet back from the street, on high land. It is 122 feet deep, the first twenty feet being bored through compact earth and clay, and the remaining 102 feet through rock and seams of earth. The water is supposed to come from a point 100 feet below the surface. It is sold to customers in the city of Topeka. The proprietor of the well is John W. Newbury.

Capital Well
Grams per liter
Ions   Radicals
Sodium (Na) .3608   Sodium oxid (Na2O) .4858
Calcium (Ca) .1832   Calcium oxid (CaO) .2559
Magnesium (Mg) .0713   Magnesium oxid (MgO) .1183
Iron (Fe) .0865   Iron oxid (FeO) .1113
Chlorin (Cl) .3200   Chlorin (Cl) .3200
Sulfuric acid ion (SO4) .2224   Sulfuric anhydrid (SO3) .1710
Silicic acid ion (SiO3) .3098   Silica (SiO2) .2400
    Organic matter trace
    Carbonic anhydrid (CO2) .8810
    Water (H2O) .1640
    Oxygen equivalent .0755
  Total 2.6718

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .4997 29.1874
Sodium sulfate (Na2SO4) .3920 22.8967
Calcium bicarbonate (CaH2(CO3)2) .7400 43.2234
Magnesium bicarbonate (MgH2(CO3)2) .4320 25.2331
Iron bicarbonate (FeH2(CO3)2) .2751 16.0744
Silica (SiO2) .2400 14.0184
Carbonic anhydrid (CO2) .0930 5.4321
Organic matter trace trace
Totals 2.6718 156.0655
Analysis by J. T. Lovewell

Wetmore, Nemaha County

The Wetmore mineral springs, which have been known for over thirty years, are situated inside the city limits of Wetmore, not more than a quarter of a mile from the center of the town. There is one large spring here and several small ones. A building is being erected here for the bottling works and bathhouse by the Wetmore Springs Mineral Water Company, under the direction of Chas. S. Lochnane. There are good hotels in the town, as well as private boarding-houses. The analysis of the water was made several years ago. Wetmore is on the line of the Central Branch Missouri Pacific railroad, forty-three miles west of Atchison.

Wetmore Mineral Springs, Spring No. 1
Ions Grams
per liter
Sodim (Na) .0241
Potassium (K) .0582
Calcium (Ca) .0888
Magnesium (Mg) .0807
Iron (Fe) .0214
Chlorin (Cl) .0323
Sulfuric acid ion (SO4) .2201
Silicic acid ion (SiOs) .0289
Phosphoric acid ion (PO4) .0033

Hypothetically combined as follows:

  Grams
per liter
Grains
per gallon
Sodium chlorid (NaCl) .0445 2.600
Sodium bicarbonate (NaHCO3) .0201 1.172
Potassium chlorid (KCl) .0111 .647
Calcium sulfate (CaSO4) .1272 7.440
Calcium phosphate (Ca3(PO4)2) .0070 .409
Calcium bicarbonate (CaH2(CO3)2) .1978 11.534
Magnesium sulfate (MgSO4) .1614 9.433
Magnesium bicarbonate (MgH2(CO3)2) .2942 17.197
Iron bicarbonate (FeH2(CO3)2) .0682 3.986
Silica (SiO2) .0228 1.330
Organic matter .0281 1.640
Totals .9824 57.388
Specific gravity, 1.0068
Temperature, 10° C. (50° F.)
Analysis by Juan H. Wright, M. D.

Comparison of Similar Waters

Excelsior Springs, Mo., Regent Spring

Grains per gallon
Analysis by Woodward and Robertson
Sodium chlorid 2.230
Potassium chlorid .670
Calcium bicarbonate 28.867
Magnesium chlorid .420
Magnesium bicarbonate 3.754
Magnesium sulfate .350
Ferrous bicarbonate 3.438
Manganese bicarbonate .982
Alumina .297
Silica 1.116
Oxygen .1998
Total 42.124

Monroe County, Wisconsin, Spata Artesian Well

Grains per gallon
Analysis by J. M. Hirsch
Sodium chlorid .112
Sodium sulfate 1.840
Sodium carbonate .120
Sodium phosphate .056
Potassium sulfate .528
Lithium carbonate .016
Calcium chlorid .504
Calcium sulfate .144
Calcium carbonate .232
Magnesium carbonate 1.992
Strontium carbonate .008
Ferrous carbonate 8.664
Aluminum phosphate .048
Silica .232
Total 14.496

Rock Enon Springs, Frederick County, Virginia, Copper Spring

Grains per gallon
Analysis by Gale and Mew
Sodium carbonate 1.21
Calcium sulfate 3.56
Calcium carbonate 5.13
Magnesium chlorid 1.12
Magnesium sulfate 12.89
Ferrous carbonate 14.25
Manganese carbonate 1.05
Alumina .80
Silica .42
Total 40.43

Schwalbach, Germany, Stablbrunnen

Grains per gallon
Analysis by Fresenius
Sodium sulfate .461
Sodium bicarbonate 1.347
Potassium sulfate .216
Potassium chlorid .391
Calcium bicarbonate 14.542
Magnesium bicarbonate 14.138
Manganese bicarbonate 1.196
Ferrous bicarbonate 5.445
Silica 1.869
Total 39.605

Marienbad, Germany, Ambrosius brunn

Grains per gallon
Analysis by Gintl
Sodium chlorid .806
Sodium sulfate 18.189
Sodium bicarbonate 4.824
Sodium nitrate .041
Potassium sulfate 2.021
Lithium carbonate .041
Calcium sulfate 2.675
Calcium bicarbonate 17.534
Magnesium chlorid 1.466
Magnesium bicarbonate 16.863
Iron bicarbonate 9.737
Manganese bicarbonate .146
Aluminous phosphate .309
Silica 2.909
Carbon dioxid (free) 134.010
Total 211.571

There are some waters that contain larger amounts of iron than those just mentioned, but, on account of the presence in these waters of much sulfuric acid, the iron is usually considered to be combined as iron sulfate. Aluminum sulfate is very often present in large quantities in these waters, as they may be formed by the decomposition and oxidation of shale containing pyrite. The latter on being oxidized furnishes both the iron and the sulfate ion. The excess of the sulfate dissolves the alumina in the shale. The following may be considered as typical waters of this class, and are classified as chalybeate by many authors:

Bath Alum Springs, Virginia, No. 2

Grains per gallon
Analysis by W. H. Taylor
Sodium chlorid .11
Sodium sulfate 1.13
Potassium sulfate .34
Calcium sulfate 1.71
Magnesium sulfate .46
Iron persulfate 26.78
Manganese sulfate .03
Aluminum sulfate 29.99
Sulfuric acid 2.88
Silica 1.95
Total 65.38

Brighton, England

Grains per gallon
Analysis by Marcet
Sodium chlorid 12.241
Calcium sulfate 32.72
Magnesium chlorid 6.00
Ferrous sulfate 14.40
Silica 1.12
Loss 1.52
Total 68.00
Carbon dioxid, 20 cubic inches.

A Comparison of Some of the Waters of the Iron Group

These waters are mainly carbonates, containing larger quantities of iron than usual. The other substances of importance are calcium and magnesium bicarbonates. The amount of iron bicarbonate in the different waters discussed is as follows:

Grains per gallon
Lawrence city supply 1.830
Coyville 2.184
Coyville, MnH2(CO3)2 3.697
Arrington No. 2 3.084
McDuff's spring 3.109
Forest Lake well 3.505
Louisville 3.691
Wetmore 3.986
Forest Lake spring 5.263
Arrington No. 1 5.484
Muscotah 6.547
Arrington No. 3 7.044
Bonner No. 5 7.603
Bonner No. 6 8.870
Bonner No. 4 10.135
Atchison electric light 12.511
Capital 16.074
Parkhurst 17.244
Parkhurst, MnH2(CO3)2 .271
Regent, Excelsior Springs, Mo 3.483
Regent, Excelsior Springs, Mo., MnH2(CO3)2 .982
Schwalbach, Germany 5.445
Schwalbach, Germany, MnH2(CO3)2 1.196
Sparta, Wis 8.644
Marienbad, Germany 9.734
Marienbad, MnH2(CO3)2 .146
Rock Enon, Va 14.250
Bath Alum, Va., (iron persulfate) 26.78
Brighton, England (ferrous sulfate) 26.78

Prev Page--Waters of Kansas--Sulfid || Next Page--Waters of Kansas--Special

Kansas Geological Survey, Geology
Placed on web April 7, 2017; originally published 1902.
Comments to webadmin@kgs.ku.edu
The URL for this page is http://www.kgs.ku.edu/Publications/Bulletins/Vol7/18_iron.html